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Bipyridine complexes of E(3+) (E = P, As, Sb, Bi): strong Lewis acids, sources of E(OTf)(3) and synthons for E(I) and E(V) cations

Triflate salts of trications [(bipy)(2)E](3+) ([6E][OTf](3)) and [(tbbipy)(2)E](3+) ([6′E][OTf](3)) (bipy = 2,2′-bipyridine, tbbipy = 4,4′-di-(t)butyl-2,2′-bipyridine; E = P, As, Sb, Bi) have been synthesized and comprehensively characterized. The unique molecular and electronic structures of this n...

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Detalles Bibliográficos
Autores principales:	Chitnis, Saurabh S., Robertson, Alasdair P. M., Burford, Neil, Patrick, Brian O., McDonald, Robert, Ferguson, Michael J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054056/ https://www.ncbi.nlm.nih.gov/pubmed/30090272 http://dx.doi.org/10.1039/c5sc02423d

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