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Uranium and thorium complexes of the phosphaethynolate ion

New tris-amidinate actinide (Th, U) complexes containing a rare O-bound terminal phosphaethynolate (OCP(–)) ligand were synthesized and fully characterized. The cyanate (OCN(–)) and thiocyanate (SCN(–)) analogs were prepared for comparison and feature a preferential N-coordination to the actinide me...

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Detalles Bibliográficos
Autores principales:	Camp, Clément, Settineri, Nicholas, Lefèvre, Julia, Jupp, Andrew R., Goicoechea, José M., Maron, Laurent, Arnold, John
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054101/ https://www.ncbi.nlm.nih.gov/pubmed/30090257 http://dx.doi.org/10.1039/c5sc02150b

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