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Cooperative benzylic–oxyallylic stabilized cations: regioselective construction of α-quaternary centers in ketone-derived compounds

We describe a novel reactivity of benzylic–stabilized oxyallyl cations towards regioselective construction of carbon quaternary centers. These synthetically useful intermediates were readily generated upon ionization of aryl substituted α-hydroxy methylenol ethers with catalytic, mild Brønsted acid....

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Detalles Bibliográficos
Autores principales:	Dange, Nitin S., Stepherson, Jacob R., Ayala, Caitlan E., Fronczek, Frank R., Kartika, Rendy
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054113/ https://www.ncbi.nlm.nih.gov/pubmed/30090249 http://dx.doi.org/10.1039/c5sc01914a

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