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Liquid-crystalline calcium carbonate: biomimetic synthesis and alignment of nanorod calcite

Liquid-crystalline CaCO(3) has been prepared for the first time. The nanorods of CaCO(3) calcite are obtained by bio-inspired crystallization through aqueous colloidal precursors of amorphous CaCO(3) stabilized by poly(acrylic acid). The synthesized calcite nanocrystals have well-tuned morphologies...

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Detalles Bibliográficos
Autores principales: Nakayama, Masanari, Kajiyama, Satoshi, Nishimura, Tatsuya, Kato, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054116/
https://www.ncbi.nlm.nih.gov/pubmed/30090240
http://dx.doi.org/10.1039/c5sc01820j
Descripción
Sumario:Liquid-crystalline CaCO(3) has been prepared for the first time. The nanorods of CaCO(3) calcite are obtained by bio-inspired crystallization through aqueous colloidal precursors of amorphous CaCO(3) stabilized by poly(acrylic acid). The synthesized calcite nanocrystals have well-tuned morphologies that are preferable for formation of liquid-crystalline phases in concentrated aqueous colloidal solution. The one-dimensional alignment of calcite crystals is achieved by mechanical shearing of the aqueous colloidal solution showing liquid-crystalline phases. These CaCO(3)-based liquid crystals formed by a self-organization process in mild conditions may have great potential for use as environmentally friendly materials.