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Similar ligand–metal bonding for transition metals and actinides? 5f(1) U(C(7)H(7))(2)(–)versus 3d(n) metallocenes
U(C(7)H(7))(2)(–) is a fascinating 5f(1) complex whose metal–ligand bonding was assigned in the literature as being very similar to 3d(7) cobaltocene, based on a crystal-field theoretical interpretation of the experimental magnetic resonance data. The present work provides an in-depth theoretical st...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6063092/ https://www.ncbi.nlm.nih.gov/pubmed/30123484 http://dx.doi.org/10.1039/c7sc05373h |