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Electrophile-promoted Fe-to-N(2) hydride migration in highly reduced Fe(N(2))(H) complexes
One of the emerging challenges associated with developing robust synthetic nitrogen fixation catalysts is the competitive formation of hydride species that can play a role in catalyst deactivation or lead to undesired hydrogen evolution reactivity (HER). It is hence desirable to devise synthetic sys...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6063139/ https://www.ncbi.nlm.nih.gov/pubmed/30123481 http://dx.doi.org/10.1039/c8sc02380h |