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Electrophile-promoted Fe-to-N(2) hydride migration in highly reduced Fe(N(2))(H) complexes

One of the emerging challenges associated with developing robust synthetic nitrogen fixation catalysts is the competitive formation of hydride species that can play a role in catalyst deactivation or lead to undesired hydrogen evolution reactivity (HER). It is hence desirable to devise synthetic sys...

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Detalles Bibliográficos
Autores principales:	Deegan, Meaghan M., Peters, Jonas C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6063139/ https://www.ncbi.nlm.nih.gov/pubmed/30123481 http://dx.doi.org/10.1039/c8sc02380h

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