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Efficient catenane synthesis by cucurbit[6]uril-mediated azide–alkyne cycloaddition

We report here the efficient synthesis of a series of [3]catenanes featuring the use of cucurbit[6]uril to simultaneously mediate the mechanical and covalent bond formations. By coupling the mechanical interlocking with covalent macrocyclization, formation of topological isomers is eliminated and th...

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Detalles Bibliográficos
Autores principales: Ng, Antony Wing Hung, Yee, Chi-Chung, Wang, Kai, Au-Yeung, Ho Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6071691/
https://www.ncbi.nlm.nih.gov/pubmed/30112089
http://dx.doi.org/10.3762/bjoc.14.158