The crystal structure of bis­[(E)-4-bromo-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenol]nickel(II) bis­[(E)-4-bromo-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolato]nickel(II) bis(perchlorate) methanol monosolvate, a structure containing strong inter-species hydrogen bonds

The title compound, [Ni(C(14)H(12)BrN(2)O)(2)][Ni(C(14)H(13)BrN(2)O)(2)](ClO(4))(2)·CH(3)OH consists of two mononuclear ([Ni(HL)(2)](2+) and [NiL (2)]) complex mol­ecules linked by strong hydrogen bonding [O⋯O separations of only 2.430 (5) Å], which is the shortest reported to date for such species....

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Detalles Bibliográficos
Autores principales: Okeke, Ugochukwu, Otchere, Raymond, Gultneh, Yilma, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6072980/
https://www.ncbi.nlm.nih.gov/pubmed/30116575
http://dx.doi.org/10.1107/S2056989018010277

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