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The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions
In the molecule of the title compound, C(15)H(14)N(2)O(2), the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C—H⋯O hydrogen bonds and ni...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6072986/ https://www.ncbi.nlm.nih.gov/pubmed/30116564 http://dx.doi.org/10.1107/S2056989018009544 |
Sumario: | In the molecule of the title compound, C(15)H(14)N(2)O(2), the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions links the molecules into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds. |
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