Cargando…
The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions
In the molecule of the title compound, C(15)H(14)N(2)O(2), the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C—H⋯O hydrogen bonds and ni...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2018
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6072986/ https://www.ncbi.nlm.nih.gov/pubmed/30116564 http://dx.doi.org/10.1107/S2056989018009544 |
| _version_ | 1783344091831992320 |
|---|---|
| author | Girisha, Marisiddaiah Sagar, Belakavadi K. Yathirajan, Hemmige S. Rathore, Ravindranath S. Glidewell, Christopher |
| author_facet | Girisha, Marisiddaiah Sagar, Belakavadi K. Yathirajan, Hemmige S. Rathore, Ravindranath S. Glidewell, Christopher |
| author_sort | Girisha, Marisiddaiah |
| collection | PubMed |
| description | In the molecule of the title compound, C(15)H(14)N(2)O(2), the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions links the molecules into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds. |
| format | Online Article Text |
| id | pubmed-6072986 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2018 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-60729862018-08-16 The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions Girisha, Marisiddaiah Sagar, Belakavadi K. Yathirajan, Hemmige S. Rathore, Ravindranath S. Glidewell, Christopher Acta Crystallogr E Crystallogr Commun Research Communications In the molecule of the title compound, C(15)H(14)N(2)O(2), the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions links the molecules into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds. International Union of Crystallography 2018-07-10 /pmc/articles/PMC6072986/ /pubmed/30116564 http://dx.doi.org/10.1107/S2056989018009544 Text en © Girisha et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Girisha, Marisiddaiah Sagar, Belakavadi K. Yathirajan, Hemmige S. Rathore, Ravindranath S. Glidewell, Christopher The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions |
| title | The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions |
| title_full | The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions |
| title_fullStr | The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions |
| title_full_unstemmed | The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions |
| title_short | The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H⋯O hydrogen bonds and nitro⋯π(arene) interactions |
| title_sort | crystal structure of (e)-2-ethyl-n-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by c—h⋯o hydrogen bonds and nitro⋯π(arene) interactions |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6072986/ https://www.ncbi.nlm.nih.gov/pubmed/30116564 http://dx.doi.org/10.1107/S2056989018009544 |
| work_keys_str_mv | AT girishamarisiddaiah thecrystalstructureofe2ethyln4nitrobenzylideneanilinethreedimensionalsupramolecularassemblymediatedbychohydrogenbondsandnitropareneinteractions AT sagarbelakavadik thecrystalstructureofe2ethyln4nitrobenzylideneanilinethreedimensionalsupramolecularassemblymediatedbychohydrogenbondsandnitropareneinteractions AT yathirajanhemmiges thecrystalstructureofe2ethyln4nitrobenzylideneanilinethreedimensionalsupramolecularassemblymediatedbychohydrogenbondsandnitropareneinteractions AT rathoreravindranaths thecrystalstructureofe2ethyln4nitrobenzylideneanilinethreedimensionalsupramolecularassemblymediatedbychohydrogenbondsandnitropareneinteractions AT glidewellchristopher thecrystalstructureofe2ethyln4nitrobenzylideneanilinethreedimensionalsupramolecularassemblymediatedbychohydrogenbondsandnitropareneinteractions AT girishamarisiddaiah crystalstructureofe2ethyln4nitrobenzylideneanilinethreedimensionalsupramolecularassemblymediatedbychohydrogenbondsandnitropareneinteractions AT sagarbelakavadik crystalstructureofe2ethyln4nitrobenzylideneanilinethreedimensionalsupramolecularassemblymediatedbychohydrogenbondsandnitropareneinteractions AT yathirajanhemmiges crystalstructureofe2ethyln4nitrobenzylideneanilinethreedimensionalsupramolecularassemblymediatedbychohydrogenbondsandnitropareneinteractions AT rathoreravindranaths crystalstructureofe2ethyln4nitrobenzylideneanilinethreedimensionalsupramolecularassemblymediatedbychohydrogenbondsandnitropareneinteractions AT glidewellchristopher crystalstructureofe2ethyln4nitrobenzylideneanilinethreedimensionalsupramolecularassemblymediatedbychohydrogenbondsandnitropareneinteractions |