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Crystal structure of a dinuclear ruthenium(II) complex with a bent CO(2) (2−) bridge
The molecular and crystal structures of a CO(2) (2−)-bridged dinuclear ruthenium complex is reported, namely, μ-carbonito-κ(2) C:O-bis[bis(2,2′-bipyridine-κ(2) N,N′)carbonylruthenium(II)] bis(hexafluoridophosphate)–acetonitrile–diethyl ether (1/1/0.5), [Ru(2)(CO)(2)(C(10)H(8)N(2))(4)(μ:κ (2)...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6072990/ https://www.ncbi.nlm.nih.gov/pubmed/30116570 http://dx.doi.org/10.1107/S2056989018009921 |
Sumario: | The molecular and crystal structures of a CO(2) (2−)-bridged dinuclear ruthenium complex is reported, namely, μ-carbonito-κ(2) C:O-bis[bis(2,2′-bipyridine-κ(2) N,N′)carbonylruthenium(II)] bis(hexafluoridophosphate)–acetonitrile–diethyl ether (1/1/0.5), [Ru(2)(CO)(2)(C(10)H(8)N(2))(4)(μ:κ (2)-C:O-CO(2))](PF(6))(2)·CH(3)CN·0.5C(4)H(10)O. The complex cation in the title compound consists of two {Ru(CO)(bpy)(2)}(2+) units (bpy = 2,2′-bipyridine) singly bridged by a μ:κ(2)-C:O carbonite anion, resulting in an unsymmetrical dinuclear structure. Some of the interatomic C⋯O distances involving the carbonyl ligands are shorter than the sum of the van der Waals radii. There are intramolecular C—H⋯O and aromatic π–π contacts in the cationic complex. In the crystal, the cations are linked by pairs of C—H⋯F hydrogen bonds in addition to weak C—H⋯F interactions between the solvent molecules and PF(6) (−) counter-anions. The equatorial F atoms of one of the PF(6) (−) anions are disordered over two sets of sites with an occupancy ratio of 0.908 (7):0.092 (7) while the central O atom of the diethyl ether solvent molecule is disordered over an inversion centre. |
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