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Crystal structure of N-allyl-4-methylbenzenesulfonamide
The title compound, C(10)H(13)NO(2)S, was synthesized by a nucleophilic substitution reaction between allyl amine and p-toluenesulfonyl chloride. The sulfonate S—O bond lengths are 1.4282 (17) and 1.4353 (17) Å, and the C—N—S—C torsion angle involving the sulfonamide moiety is −61.0 (2)°. In the cr...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6072992/ https://www.ncbi.nlm.nih.gov/pubmed/30116576 http://dx.doi.org/10.1107/S2056989018010290 |
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| author | Patel, Zeel S. Stevens, Amanda C. Bookout, Erin C. Staples, Richard J. Biros, Shannon M. Ngassa, Felix N. |
| author_facet | Patel, Zeel S. Stevens, Amanda C. Bookout, Erin C. Staples, Richard J. Biros, Shannon M. Ngassa, Felix N. |
| author_sort | Patel, Zeel S. |
| collection | PubMed |
| description | The title compound, C(10)H(13)NO(2)S, was synthesized by a nucleophilic substitution reaction between allyl amine and p-toluenesulfonyl chloride. The sulfonate S—O bond lengths are 1.4282 (17) and 1.4353 (17) Å, and the C—N—S—C torsion angle involving the sulfonamide moiety is −61.0 (2)°. In the crystal, centrosymmetric dimers of the title compound are present via intermolecular N—H⋯O hydrogen bonds between sulfonamide groups. These dimers are linked into ribbons along the c-axis direction through offset π–π interactions. |
| format | Online Article Text |
| id | pubmed-6072992 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2018 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-60729922018-08-16 Crystal structure of N-allyl-4-methylbenzenesulfonamide Patel, Zeel S. Stevens, Amanda C. Bookout, Erin C. Staples, Richard J. Biros, Shannon M. Ngassa, Felix N. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(10)H(13)NO(2)S, was synthesized by a nucleophilic substitution reaction between allyl amine and p-toluenesulfonyl chloride. The sulfonate S—O bond lengths are 1.4282 (17) and 1.4353 (17) Å, and the C—N—S—C torsion angle involving the sulfonamide moiety is −61.0 (2)°. In the crystal, centrosymmetric dimers of the title compound are present via intermolecular N—H⋯O hydrogen bonds between sulfonamide groups. These dimers are linked into ribbons along the c-axis direction through offset π–π interactions. International Union of Crystallography 2018-07-20 /pmc/articles/PMC6072992/ /pubmed/30116576 http://dx.doi.org/10.1107/S2056989018010290 Text en © Patel et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Patel, Zeel S. Stevens, Amanda C. Bookout, Erin C. Staples, Richard J. Biros, Shannon M. Ngassa, Felix N. Crystal structure of N-allyl-4-methylbenzenesulfonamide |
| title | Crystal structure of N-allyl-4-methylbenzenesulfonamide |
| title_full | Crystal structure of N-allyl-4-methylbenzenesulfonamide |
| title_fullStr | Crystal structure of N-allyl-4-methylbenzenesulfonamide |
| title_full_unstemmed | Crystal structure of N-allyl-4-methylbenzenesulfonamide |
| title_short | Crystal structure of N-allyl-4-methylbenzenesulfonamide |
| title_sort | crystal structure of n-allyl-4-methylbenzenesulfonamide |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6072992/ https://www.ncbi.nlm.nih.gov/pubmed/30116576 http://dx.doi.org/10.1107/S2056989018010290 |
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