(2R,3R)-1,4-Dioxa­spiro­[4.4]nonane-2,3-di­carb­oxy­lic and (2R,3R)-1,4-dioxa­spiro­[4.5]decane-2,3-di­carb­oxy­lic acids

The title compounds, C(9)H(12)O(6) and C(10)H(14)O(6), were formed by careful hydrolysis of the corresponding diethyl esters. Their single crystals were grown from an ethyl acetate/hexane mixture. Crystals of both compounds have monoclinic (P2(1)) symmetry with a single mol­ecule in the asymmetric u...

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Autores principales: Minyaev, Mikhail E., Roitershtein, Dmitrii M., Vinogradov, Alexey A., Ananyev, Ivan V., Nifant’ev, Ilya E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6073000/
https://www.ncbi.nlm.nih.gov/pubmed/30116561
http://dx.doi.org/10.1107/S2056989018009593
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author Minyaev, Mikhail E.
Roitershtein, Dmitrii M.
Vinogradov, Alexey A.
Ananyev, Ivan V.
Nifant’ev, Ilya E.
author_facet Minyaev, Mikhail E.
Roitershtein, Dmitrii M.
Vinogradov, Alexey A.
Ananyev, Ivan V.
Nifant’ev, Ilya E.
author_sort Minyaev, Mikhail E.
collection PubMed
description The title compounds, C(9)H(12)O(6) and C(10)H(14)O(6), were formed by careful hydrolysis of the corresponding diethyl esters. Their single crystals were grown from an ethyl acetate/hexane mixture. Crystals of both compounds have monoclinic (P2(1)) symmetry with a single mol­ecule in the asymmetric unit. Both crystal structures are very similar and display four –CO—OH⋯O=C(OH)– hydrogen bonds, forming a two-dimensional double-layered framework.
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spelling pubmed-60730002018-08-16 (2R,3R)-1,4-Dioxa­spiro­[4.4]nonane-2,3-di­carb­oxy­lic and (2R,3R)-1,4-dioxa­spiro­[4.5]decane-2,3-di­carb­oxy­lic acids Minyaev, Mikhail E. Roitershtein, Dmitrii M. Vinogradov, Alexey A. Ananyev, Ivan V. Nifant’ev, Ilya E. Acta Crystallogr E Crystallogr Commun Research Communications The title compounds, C(9)H(12)O(6) and C(10)H(14)O(6), were formed by careful hydrolysis of the corresponding diethyl esters. Their single crystals were grown from an ethyl acetate/hexane mixture. Crystals of both compounds have monoclinic (P2(1)) symmetry with a single mol­ecule in the asymmetric unit. Both crystal structures are very similar and display four –CO—OH⋯O=C(OH)– hydrogen bonds, forming a two-dimensional double-layered framework. International Union of Crystallography 2018-07-06 /pmc/articles/PMC6073000/ /pubmed/30116561 http://dx.doi.org/10.1107/S2056989018009593 Text en © Minyaev et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Minyaev, Mikhail E.
Roitershtein, Dmitrii M.
Vinogradov, Alexey A.
Ananyev, Ivan V.
Nifant’ev, Ilya E.
(2R,3R)-1,4-Dioxa­spiro­[4.4]nonane-2,3-di­carb­oxy­lic and (2R,3R)-1,4-dioxa­spiro­[4.5]decane-2,3-di­carb­oxy­lic acids
title (2R,3R)-1,4-Dioxa­spiro­[4.4]nonane-2,3-di­carb­oxy­lic and (2R,3R)-1,4-dioxa­spiro­[4.5]decane-2,3-di­carb­oxy­lic acids
title_full (2R,3R)-1,4-Dioxa­spiro­[4.4]nonane-2,3-di­carb­oxy­lic and (2R,3R)-1,4-dioxa­spiro­[4.5]decane-2,3-di­carb­oxy­lic acids
title_fullStr (2R,3R)-1,4-Dioxa­spiro­[4.4]nonane-2,3-di­carb­oxy­lic and (2R,3R)-1,4-dioxa­spiro­[4.5]decane-2,3-di­carb­oxy­lic acids
title_full_unstemmed (2R,3R)-1,4-Dioxa­spiro­[4.4]nonane-2,3-di­carb­oxy­lic and (2R,3R)-1,4-dioxa­spiro­[4.5]decane-2,3-di­carb­oxy­lic acids
title_short (2R,3R)-1,4-Dioxa­spiro­[4.4]nonane-2,3-di­carb­oxy­lic and (2R,3R)-1,4-dioxa­spiro­[4.5]decane-2,3-di­carb­oxy­lic acids
title_sort (2r,3r)-1,4-dioxa­spiro­[4.4]nonane-2,3-di­carb­oxy­lic and (2r,3r)-1,4-dioxa­spiro­[4.5]decane-2,3-di­carb­oxy­lic acids
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6073000/
https://www.ncbi.nlm.nih.gov/pubmed/30116561
http://dx.doi.org/10.1107/S2056989018009593
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