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Crystal structure and Hirshfeld surface analysis of (E)-3-(2-chloro-4-fluoro­phen­yl)-1-(2,5-di­chloro­thio­phen-3-yl)prop-2-en-1-one

In the title chalcone–thio­phene derivative, C(13)H(6)Cl(3)FOS, the aromatic rings are inclined to one another by 12.9 (2)°, and the thio­phene ring is affected by π-conjugation. In the crystal, mol­ecules are linked by C—H⋯F hydrogen bonds, forming an R (2) (2)(8) ring motif. A Hirshfeld surface an...

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Detalles Bibliográficos
Autores principales: Sanjeeva Murthy, T. N., Naveen, S., Chidan Kumar, C. S., Veeraiah, M. K., Quah, Ching Kheng, Siddaraju, B. P., Warad, Ismail
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6073002/
https://www.ncbi.nlm.nih.gov/pubmed/30116578
http://dx.doi.org/10.1107/S2056989018010216
Descripción
Sumario:In the title chalcone–thio­phene derivative, C(13)H(6)Cl(3)FOS, the aromatic rings are inclined to one another by 12.9 (2)°, and the thio­phene ring is affected by π-conjugation. In the crystal, mol­ecules are linked by C—H⋯F hydrogen bonds, forming an R (2) (2)(8) ring motif. A Hirshfeld surface analysis was conducted to verify the contribution of the different inter­molecular inter­actions. The shape-index surface clearly shows that the two sides of the mol­ecules are involved in the same contacts with neighbouring mol­ecules and the curvedness plots show flat surface patches characteristic of planar stacking.