Cargando…
Crystal structure and Hirshfeld surface analysis of ethyl (E)-4-[(4-hydroxy-3-methoxy-5-nitrobenzylidene)amino]benzoate
The title Schiff base compound, C(17)H(16)N(2)O(6), has an E configuration with respect to the C=N bond, with a dihedral angle between the two benzene rings of 31.90 (12)°. There is an intramolecular O—H⋯O(nitro) hydrogen bond present forming an S(6) ring motif. In the crystal, molecules are linke...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6073003/ https://www.ncbi.nlm.nih.gov/pubmed/30116566 http://dx.doi.org/10.1107/S2056989018009465 |
Sumario: | The title Schiff base compound, C(17)H(16)N(2)O(6), has an E configuration with respect to the C=N bond, with a dihedral angle between the two benzene rings of 31.90 (12)°. There is an intramolecular O—H⋯O(nitro) hydrogen bond present forming an S(6) ring motif. In the crystal, molecules are linked by pairs of O—H⋯O hydrogen bonds, forming inversion dimers enclosing an R (2) (2)(4) ring motif. The dimers are linked about an inversion centre by pairs of C—H⋯O hydrogen bonds, which enclose R (2) (2)(22) loops, forming chains propagating along the [10[Image: see text]] direction. Hirshfeld surface analysis and fingerprint plots show enrichment ratios for the H⋯H, O⋯H and C⋯H contacts, indicating a high propensity of such interactions in the crystal. Both the nitro group and the CH(3)–CH(2)–O– group are positionally disordered. |
---|