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Crystal structure and Hirshfeld surface analysis of N,N′-bis(3-tert-butyl-2-hydroxy-5-methylbenzylidene)ethane-1,2-diamine
The title compound, C(26)H(36)N(2)O(2), crystallizes in the phenol–imine form. In the molecule, there are intramolecular O—H⋯N hydrogen bonds forming S(6) ring motifs, and the two aromatic rings are inclined to each other by 37.9 (7)°. In the crystal, molecules are linked by pairs of weak C—H⋯O h...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6073007/ https://www.ncbi.nlm.nih.gov/pubmed/30116581 http://dx.doi.org/10.1107/S2056989018009726 |
Sumario: | The title compound, C(26)H(36)N(2)O(2), crystallizes in the phenol–imine form. In the molecule, there are intramolecular O—H⋯N hydrogen bonds forming S(6) ring motifs, and the two aromatic rings are inclined to each other by 37.9 (7)°. In the crystal, molecules are linked by pairs of weak C—H⋯O hydrogen bonds, forming inversion dimers. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H⋯H (77.5%), H⋯C/C⋯H (16%), H⋯O/O⋯H (3.1%) and H⋯N/N⋯H (1.7%) interactions. |
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