Crystal structure of aqua­(2-{[2-({2-[bis­(carboxyl­ato-κO-meth­yl)amino-κN]eth­yl}(carboxyl­ato-κO-meth­yl)amino-κN)eth­yl](carb­oxy­meth­yl)aza­niumyl}acetato)­gallium(III) trihydrate

In the title Ga(III) complex compound with pentetic acid, [Ga(C(14)H(20)N(3)O(10))(H(2)O)]·3H(2)O, the Ga(III) centre is bound in a slightly distorted octa­hedral coordination sphere by two amine N atoms, three carboxyl­ate O atoms and one water O atom. The complex mol­ecule exists as a zwitterion....

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Autores principales: Wallin, Martin, Turner, Peter, Katsifis, Andrew, Yang, Mingshi, Chan, Hak-Kim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6073008/
https://www.ncbi.nlm.nih.gov/pubmed/30116560
http://dx.doi.org/10.1107/S2056989018009428
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author Wallin, Martin
Turner, Peter
Katsifis, Andrew
Yang, Mingshi
Chan, Hak-Kim
author_facet Wallin, Martin
Turner, Peter
Katsifis, Andrew
Yang, Mingshi
Chan, Hak-Kim
author_sort Wallin, Martin
collection PubMed
description In the title Ga(III) complex compound with pentetic acid, [Ga(C(14)H(20)N(3)O(10))(H(2)O)]·3H(2)O, the Ga(III) centre is bound in a slightly distorted octa­hedral coordination sphere by two amine N atoms, three carboxyl­ate O atoms and one water O atom. The complex mol­ecule exists as a zwitterion. In the crystal, the complexes are linked to each other via O—H⋯O and C—H⋯O hydrogen bonds, forming layers parallel to (001). Three uncoordinating water mol­ecules link the complex layers via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-60730082018-08-16 Crystal structure of aqua­(2-{[2-({2-[bis­(carboxyl­ato-κO-meth­yl)amino-κN]eth­yl}(carboxyl­ato-κO-meth­yl)amino-κN)eth­yl](carb­oxy­meth­yl)aza­niumyl}acetato)­gallium(III) trihydrate Wallin, Martin Turner, Peter Katsifis, Andrew Yang, Mingshi Chan, Hak-Kim Acta Crystallogr E Crystallogr Commun Research Communications In the title Ga(III) complex compound with pentetic acid, [Ga(C(14)H(20)N(3)O(10))(H(2)O)]·3H(2)O, the Ga(III) centre is bound in a slightly distorted octa­hedral coordination sphere by two amine N atoms, three carboxyl­ate O atoms and one water O atom. The complex mol­ecule exists as a zwitterion. In the crystal, the complexes are linked to each other via O—H⋯O and C—H⋯O hydrogen bonds, forming layers parallel to (001). Three uncoordinating water mol­ecules link the complex layers via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2018-07-06 /pmc/articles/PMC6073008/ /pubmed/30116560 http://dx.doi.org/10.1107/S2056989018009428 Text en © Wallin et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Wallin, Martin
Turner, Peter
Katsifis, Andrew
Yang, Mingshi
Chan, Hak-Kim
Crystal structure of aqua­(2-{[2-({2-[bis­(carboxyl­ato-κO-meth­yl)amino-κN]eth­yl}(carboxyl­ato-κO-meth­yl)amino-κN)eth­yl](carb­oxy­meth­yl)aza­niumyl}acetato)­gallium(III) trihydrate
title Crystal structure of aqua­(2-{[2-({2-[bis­(carboxyl­ato-κO-meth­yl)amino-κN]eth­yl}(carboxyl­ato-κO-meth­yl)amino-κN)eth­yl](carb­oxy­meth­yl)aza­niumyl}acetato)­gallium(III) trihydrate
title_full Crystal structure of aqua­(2-{[2-({2-[bis­(carboxyl­ato-κO-meth­yl)amino-κN]eth­yl}(carboxyl­ato-κO-meth­yl)amino-κN)eth­yl](carb­oxy­meth­yl)aza­niumyl}acetato)­gallium(III) trihydrate
title_fullStr Crystal structure of aqua­(2-{[2-({2-[bis­(carboxyl­ato-κO-meth­yl)amino-κN]eth­yl}(carboxyl­ato-κO-meth­yl)amino-κN)eth­yl](carb­oxy­meth­yl)aza­niumyl}acetato)­gallium(III) trihydrate
title_full_unstemmed Crystal structure of aqua­(2-{[2-({2-[bis­(carboxyl­ato-κO-meth­yl)amino-κN]eth­yl}(carboxyl­ato-κO-meth­yl)amino-κN)eth­yl](carb­oxy­meth­yl)aza­niumyl}acetato)­gallium(III) trihydrate
title_short Crystal structure of aqua­(2-{[2-({2-[bis­(carboxyl­ato-κO-meth­yl)amino-κN]eth­yl}(carboxyl­ato-κO-meth­yl)amino-κN)eth­yl](carb­oxy­meth­yl)aza­niumyl}acetato)­gallium(III) trihydrate
title_sort crystal structure of aqua­(2-{[2-({2-[bis­(carboxyl­ato-κo-meth­yl)amino-κn]eth­yl}(carboxyl­ato-κo-meth­yl)amino-κn)eth­yl](carb­oxy­meth­yl)aza­niumyl}acetato)­gallium(iii) trihydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6073008/
https://www.ncbi.nlm.nih.gov/pubmed/30116560
http://dx.doi.org/10.1107/S2056989018009428
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