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Electrochemical and Stress Corrosion Mechanism of Submarine Pipeline in Simulated Seawater in Presence of Different Alternating Current Densities

In this study, electrochemical measurements, immersion tests, and slow strain rate tensile (SSRT) tests were applied to investigate the electrochemical and stress corrosion cracking (SCC) behavior of X70 steel in simulated seawater with the interference of different alternating current (AC) densitie...

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Detalles Bibliográficos
Autores principales: Wu, Wei, Pan, Yue, Liu, Zhiyong, Du, Cuiwei, Li, Xiaogang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6073114/
https://www.ncbi.nlm.nih.gov/pubmed/29941807
http://dx.doi.org/10.3390/ma11071074
Descripción
Sumario:In this study, electrochemical measurements, immersion tests, and slow strain rate tensile (SSRT) tests were applied to investigate the electrochemical and stress corrosion cracking (SCC) behavior of X70 steel in simulated seawater with the interference of different alternating current (AC) densities. The results indicate that AC significantly strengthens the cathodic reaction, especially the oxygen reduction reaction. Simultaneously, hydrogen evolution reaction occurs when the limiting diffusion current density of oxygen reaches, and thus, i(corr) sharply increases with the increase in AC density. Additionally, when AC is imposed, the X70 steel exhibits higher SCC susceptibility in the simulated seawater, and the susceptibility increases with the increasing AC density. The SCC mechanism is controlled by both anodic dissolution (AD) and hydrogen embrittlement (HE) with the interference of AC.