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Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018)

The Cover Feature illustrates the electrochemically catalyzed intramolecular amination reactions that result in the formation of cyclic ureas and 1,2‐difunctionalization of terminal alkenes. Several reagents and reagent combinations have been developed for the amination and functionalization of unac...

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Detalles Bibliográficos
Autores principales: Ahmed, Nisar, Khatoon, Saira
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6077875/
http://dx.doi.org/10.1002/open.201800135
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author Ahmed, Nisar
Khatoon, Saira
author_facet Ahmed, Nisar
Khatoon, Saira
author_sort Ahmed, Nisar
collection PubMed
description The Cover Feature illustrates the electrochemically catalyzed intramolecular amination reactions that result in the formation of cyclic ureas and 1,2‐difunctionalization of terminal alkenes. Several reagents and reagent combinations have been developed for the amination and functionalization of unactivated alkenes. However, most are dependent on oxidants and catalysts. A green approach is reported for the intramolecular amination of urea‐tethered alkenes by generating radicals without using expensive catalysts and employing only electricity. This method can be considered environmentally friendly given that it avoids the issues of toxicity or complicated metal ligands. More information can be found in the Full Paper by N. Ahmed and S. Khatoon on page 576 in Issue 8, 2018 (DOI: https://doi.org/10.1002/open.201800064).[Image: see text]
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spelling pubmed-60778752018-08-09 Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018) Ahmed, Nisar Khatoon, Saira ChemistryOpen Cover Pictures The Cover Feature illustrates the electrochemically catalyzed intramolecular amination reactions that result in the formation of cyclic ureas and 1,2‐difunctionalization of terminal alkenes. Several reagents and reagent combinations have been developed for the amination and functionalization of unactivated alkenes. However, most are dependent on oxidants and catalysts. A green approach is reported for the intramolecular amination of urea‐tethered alkenes by generating radicals without using expensive catalysts and employing only electricity. This method can be considered environmentally friendly given that it avoids the issues of toxicity or complicated metal ligands. More information can be found in the Full Paper by N. Ahmed and S. Khatoon on page 576 in Issue 8, 2018 (DOI: https://doi.org/10.1002/open.201800064).[Image: see text] John Wiley and Sons Inc. 2018-07-17 /pmc/articles/PMC6077875/ http://dx.doi.org/10.1002/open.201800135 Text en © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
spellingShingle Cover Pictures
Ahmed, Nisar
Khatoon, Saira
Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018)
title Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018)
title_full Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018)
title_fullStr Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018)
title_full_unstemmed Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018)
title_short Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018)
title_sort cover feature: facile electrochemical intramolecular amination of urea‐tethered terminal alkenes for the synthesis of cyclic ureas (chemistryopen 8/2018)
topic Cover Pictures
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6077875/
http://dx.doi.org/10.1002/open.201800135
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