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Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018)
The Cover Feature illustrates the electrochemically catalyzed intramolecular amination reactions that result in the formation of cyclic ureas and 1,2‐difunctionalization of terminal alkenes. Several reagents and reagent combinations have been developed for the amination and functionalization of unac...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6077875/ http://dx.doi.org/10.1002/open.201800135 |
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author | Ahmed, Nisar Khatoon, Saira |
author_facet | Ahmed, Nisar Khatoon, Saira |
author_sort | Ahmed, Nisar |
collection | PubMed |
description | The Cover Feature illustrates the electrochemically catalyzed intramolecular amination reactions that result in the formation of cyclic ureas and 1,2‐difunctionalization of terminal alkenes. Several reagents and reagent combinations have been developed for the amination and functionalization of unactivated alkenes. However, most are dependent on oxidants and catalysts. A green approach is reported for the intramolecular amination of urea‐tethered alkenes by generating radicals without using expensive catalysts and employing only electricity. This method can be considered environmentally friendly given that it avoids the issues of toxicity or complicated metal ligands. More information can be found in the Full Paper by N. Ahmed and S. Khatoon on page 576 in Issue 8, 2018 (DOI: https://doi.org/10.1002/open.201800064).[Image: see text] |
format | Online Article Text |
id | pubmed-6077875 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-60778752018-08-09 Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018) Ahmed, Nisar Khatoon, Saira ChemistryOpen Cover Pictures The Cover Feature illustrates the electrochemically catalyzed intramolecular amination reactions that result in the formation of cyclic ureas and 1,2‐difunctionalization of terminal alkenes. Several reagents and reagent combinations have been developed for the amination and functionalization of unactivated alkenes. However, most are dependent on oxidants and catalysts. A green approach is reported for the intramolecular amination of urea‐tethered alkenes by generating radicals without using expensive catalysts and employing only electricity. This method can be considered environmentally friendly given that it avoids the issues of toxicity or complicated metal ligands. More information can be found in the Full Paper by N. Ahmed and S. Khatoon on page 576 in Issue 8, 2018 (DOI: https://doi.org/10.1002/open.201800064).[Image: see text] John Wiley and Sons Inc. 2018-07-17 /pmc/articles/PMC6077875/ http://dx.doi.org/10.1002/open.201800135 Text en © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim |
spellingShingle | Cover Pictures Ahmed, Nisar Khatoon, Saira Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018) |
title | Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018) |
title_full | Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018) |
title_fullStr | Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018) |
title_full_unstemmed | Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018) |
title_short | Cover Feature: Facile Electrochemical Intramolecular Amination of Urea‐Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas (ChemistryOpen 8/2018) |
title_sort | cover feature: facile electrochemical intramolecular amination of urea‐tethered terminal alkenes for the synthesis of cyclic ureas (chemistryopen 8/2018) |
topic | Cover Pictures |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6077875/ http://dx.doi.org/10.1002/open.201800135 |
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