Cargando…
Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L(3)-edge X-ray absorption spectroscopy
The addition of various oxidants to the near-linear Sm(ii) complex [Sm(N(††))(2)] (1), where N(††) is the bulky bis(triisopropylsilyl)amide ligand {N(Si(i)Pr(3))(2)}, afforded a family of heteroleptic three-coordinate Sm(iii) halide complexes, [Sm(N(††))(2)(X)] (X = F, 2-F; Cl, 2-Cl; Br, 2-Br; I, 2-...
| Autores principales: | , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6083822/ https://www.ncbi.nlm.nih.gov/pubmed/29790545 http://dx.doi.org/10.1039/c8dt01452c |