Water stabilization of Zr(6)-based metal–organic frameworks via solvent-assisted ligand incorporation

Water stability in metal–organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavitie...

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Detalles Bibliográficos
Autores principales: Deria, Pravas, Chung, Yongchul G., Snurr, Randall Q., Hupp, Joseph T., Farha, Omar K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6088556/
https://www.ncbi.nlm.nih.gov/pubmed/30155009
http://dx.doi.org/10.1039/c5sc01784j
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author Deria, Pravas
Chung, Yongchul G.
Snurr, Randall Q.
Hupp, Joseph T.
Farha, Omar K.
author_facet Deria, Pravas
Chung, Yongchul G.
Snurr, Randall Q.
Hupp, Joseph T.
Farha, Omar K.
author_sort Deria, Pravas
collection PubMed
description Water stability in metal–organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.
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spelling pubmed-60885562018-08-28 Water stabilization of Zr(6)-based metal–organic frameworks via solvent-assisted ligand incorporation Deria, Pravas Chung, Yongchul G. Snurr, Randall Q. Hupp, Joseph T. Farha, Omar K. Chem Sci Chemistry Water stability in metal–organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs. Royal Society of Chemistry 2015-09-01 2015-07-01 /pmc/articles/PMC6088556/ /pubmed/30155009 http://dx.doi.org/10.1039/c5sc01784j Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Deria, Pravas
Chung, Yongchul G.
Snurr, Randall Q.
Hupp, Joseph T.
Farha, Omar K.
Water stabilization of Zr(6)-based metal–organic frameworks via solvent-assisted ligand incorporation
title Water stabilization of Zr(6)-based metal–organic frameworks via solvent-assisted ligand incorporation
title_full Water stabilization of Zr(6)-based metal–organic frameworks via solvent-assisted ligand incorporation
title_fullStr Water stabilization of Zr(6)-based metal–organic frameworks via solvent-assisted ligand incorporation
title_full_unstemmed Water stabilization of Zr(6)-based metal–organic frameworks via solvent-assisted ligand incorporation
title_short Water stabilization of Zr(6)-based metal–organic frameworks via solvent-assisted ligand incorporation
title_sort water stabilization of zr(6)-based metal–organic frameworks via solvent-assisted ligand incorporation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6088556/
https://www.ncbi.nlm.nih.gov/pubmed/30155009
http://dx.doi.org/10.1039/c5sc01784j
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AT huppjosepht waterstabilizationofzr6basedmetalorganicframeworksviasolventassistedligandincorporation
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