Cargando…

Probing Interactions between Electron Donors and the Support in MgCl(2)-Supported Ziegler–Natta Catalysts

[Image: see text] Olefin polymerization using Ziegler–Natta catalysts (ZNCs) is an important industrial process. Despite this, fundamental insight into the inner working mechanisms of these catalysts remains scarce. Here, we focus on the low-γ nuclei (25)Mg and (35)Cl for an in-depth solid-state NMR...

Descripción completa

Detalles Bibliográficos
Autores principales:	Blaakmeer, E. S. Merijn, Antinucci, Giuseppe, van Eck, Ernst R. H., Kentgens, Arno P. M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2018
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6089496/ https://www.ncbi.nlm.nih.gov/pubmed/30116465 http://dx.doi.org/10.1021/acs.jpcc.8b05123

Ejemplares similares

Structural Characterization of Electron Donors in Ziegler–Natta Catalysts
por: Blaakmeer, E. S. Merijn, et al.
Publicado: (2018)

Dataset of energetically accessible structures of MgCl(2)/TiCl(4) clusters for Ziegler-Natta catalysts
por: Takasao, Gentoku, et al.
Publicado: (2020)

Effect of EtOH/MgCl(2) Molar Ratios on the Catalytic Properties of MgCl(2)-SiO(2)/TiCl(4) Ziegler-Natta Catalyst for Ethylene Polymerization
por: Patthamasang, Supanan, et al.
Publicado: (2011)

MgCl(2)-Supported Titanium Ziegler-Natta Catalyst Using Carbon Dioxide-Based Poly(propylene ether carbonate) Diols as Internal Electron Donor for 1-Butene Polymerization
por: Cui, Xiaopeng, et al.
Publicado: (2017)

Silyl diol ester as a new selectivity control agent in MgCl(2)-supported Ziegler–Natta systems for propylene polymerization: catalyst structure and polymer properties
por: Poorsank, Fatemeh, et al.
Publicado: (2019)

Behaviors in Ethylene Polymerization of MgCl(2)-SiO(2)/TiCl(4)/THF Ziegler-Natta Catalysts with Differently Treated SiO(2)
por: Senso, Nichapat, et al.
Publicado: (2011)

A Study of Ziegler–Natta Propylene Polymerization Catalysts by Spectroscopic Methods
por: Tkachenko, Olga P., et al.
Publicado: (2017)

Study on Hydrogen Sensitivity of Ziegler–Natta Catalysts with Novel Cycloalkoxy Silane Compounds as External Electron Donor
por: Li, Hongming, et al.
Publicado: (2016)

The Influence of Mixed Activators on Ethylene Polymerization and Ethylene/1-Hexene Copolymerization with Silica-Supported Ziegler-Natta Catalyst
por: Senso, Nichapat, et al.
Publicado: (2010)

Comparative Study on Kinetics of Ethylene and Propylene Polymerizations with Supported Ziegler–Natta Catalyst: Catalyst Fragmentation Promoted by Polymer Crystalline Lamellae
por: Zhang, Zhen, et al.
Publicado: (2019)

The Influence of Ziegler-Natta and Metallocene Catalysts on Polyolefin Structure, Properties, and Processing Ability
por: Shamiri, Ahmad, et al.
Publicado: (2014)

New Insight into Titanium–Magnesium Ziegler–Natta Catalysts Using Photoluminescence Spectroscopy
por: Panchenko, Valentina N., et al.
Publicado: (2020)

Heterogeneity of Active Sites in the Polymer Chain Transfer Reactions at Olefin Polymerization over Multisite Supported Ziegler-Natta Catalysts
por: Matsko, Mikhail, et al.
Publicado: (2023)

Impact of Traces of Hydrogen Sulfide on the Efficiency of Ziegler–Natta Catalyst on the Final Properties of Polypropylene
por: Hernández-Fernández, Joaquín, et al.
Publicado: (2022)

Roles of Salicylate Donors in Enhancement of Productivity and Isotacticity of Ziegler–Natta Catalyzed Propylene Polymerization
por: Ratanasak, Manussada, et al.
Publicado: (2020)

High Melting Point of Linear, Spiral Polyethylene Nanofibers and Polyethylene Microspheres Obtained Through Confined Polymerization by a PPM‐Supported Ziegler‐Natta Catalyst
por: Xiao, Yu, et al.
Publicado: (2020)

Assessing 1,9-Decadiene/Ethylene Copolymerization with Ziegler–Natta Catalyst to Access Long Chain-Branched Polyethylene
por: Liu, Yang, et al.
Publicado: (2021)

Nano-Dispersed Ziegler-Natta Catalysts for 1 μm-Sized Ultra-High Molecular Weight Polyethylene Particles
por: Chammingkwan, Patchanee, et al.
Publicado: (2018)

A combined experimental and molecular simulation study on stress generation phenomena during the Ziegler–Natta polyethylene catalyst fragmentation process
por: De Nicola, Antonio, et al.
Publicado: (2022)

Experimental–Density Functional Theory (DFT) Study of the Inhibitory Effect of Furan Residues in the Ziegler–Natta Catalyst during Polypropylene Synthesis
por: Hernández-Fernández, Joaquín, et al.
Publicado: (2023)

Evaluation of the Reactivity of Methanol and Hydrogen Sulfide Residues with the Ziegler–Natta Catalyst during Polypropylene Synthesis and Its Effects on Polymer Properties
por: Hernández-Fernández, Joaquín, et al.
Publicado: (2023)

Durability of concretes exposed to high concentrations of CaCl(2) and MgCl(2)
por: Hosseinzadeh, Nima, et al.
Publicado: (2022)

Theoretical–Experimental Study of the Action of Trace Amounts of Formaldehyde, Propionaldehyde, and Butyraldehyde as Inhibitors of the Ziegler–Natta Catalyst and the Synthesis of an Ethylene–Propylene Copolymer
por: Hernández-Fernández, Joaquín, et al.
Publicado: (2023)

High-pressure X-ray diffraction, Raman, and computational studies of MgCl(2) up to 1 Mbar: Extensive pressure stability of the β-MgCl(2) layered structure
por: Stavrou, Elissaios, et al.
Publicado: (2016)

Effect of MgCl(2) Loading on the Yield and Performance of Cabbage-Based Biochar
por: Zhu, Cui, et al.
Publicado: (2023)

In-chain functionalized syndiotactic 1,2-polybutadiene by a Ziegler–Natta iron(iii) catalytic system
por: Liang, Shanshan, et al.
Publicado: (2019)

DFT and ONIOM Simulation of 1,3-Butadiene Polymerization Catalyzed by Neodymium-Based Ziegler–Natta System
por: Masliy, Alexey N., et al.
Publicado: (2023)

Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2)
por: Metzler, Maurice, et al.
Publicado: (2023)

Effect of Internal Donors on Raman and IR Spectroscopic Fingerprints of MgCl(2)/TiCl(4) Nanoclusters Determined by Machine Learning and DFT
por: D’Amore, Maddalena, et al.
Publicado: (2022)

Correction: In-chain functionalized syndiotactic 1,2-polybutadiene by a Ziegler–Natta iron(iii) catalytic system
por: Liang, Shanshan, et al.
Publicado: (2021)

Aliphatic Anion Exchange Ionomers with Long Spacers and No Ether Links by Ziegler–Natta Polymerization: Properties and Alkaline Stability
por: Becerra-Arciniegas, Raul Andres, et al.
Publicado: (2022)

Comparison of the reaction of bone-derived cells to enhanced MgCl(2)-salt concentrations
por: Burmester, Anna, et al.
Publicado: (2014)

Reactive Grand-Canonical Monte Carlo Simulations for Modeling Hydration of MgCl(2)
por: Heijmans, Koen, et al.
Publicado: (2021)

Development of Large-Scale Stopped-Flow Technique and its Application in Elucidation of Initial Ziegler–Natta Olefin Polymerization Kinetics
por: Thakur, Ashutosh, et al.
Publicado: (2019)

Disclosing the Interaction between Carbon Monoxide and Alkylated Ti(3+) Species: a Direct Insight into Ziegler–Natta Catalysis
por: Piovano, Alessandro, et al.
Publicado: (2020)

Thermodynamic Description of Dilution and Dissolution Processes in the MgCl(2)−CsCl−H(2)O Ternary System
por: Baranauskaite, Valeriia, et al.
Publicado: (2021)

Multisite Ion Model in Concentrated Solutions of Divalent Cations (MgCl(2) and CaCl(2)): Osmotic Pressure Calculations
por: Saxena, Akansha, et al.
Publicado: (2014)

First-Principles Study of Chemical Mixtures of CaCl(2) and MgCl(2) Hydrates for Optimized Seasonal Heat Storage
por: Pathak, A. D., et al.
Publicado: (2017)

Impact of partial substitution of NaCl by KCl, and MgCl(2) on physicochemical and sensory properties of cooked sausages during storage
por: Jin, Sang-Keun, et al.
Publicado: (2020)

Effect of MgCl(2) and GdCl(3) on ORAI1 Expression and Store-Operated Ca(2+) Entry in Megakaryocytes
por: Zhou, Kuo, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_tbjr8hntrhsk6q1jlq76oddrfj