Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde

Here we present equilibrium data for the cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K. The reaction was carried out in batch reactors, using different reactant molar ratios and the 2nd generation Ru Hovey...

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Detalles Bibliográficos
Autores principales: Nieres, Pablo D., Trasarti, Andrés F., Apesteguía, Carlos R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2018
Materias:
Chemical Engineering
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6092456/
https://www.ncbi.nlm.nih.gov/pubmed/30112434
http://dx.doi.org/10.1016/j.dib.2018.07.064
Descripción
Sumario:Here we present equilibrium data for the cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K. The reaction was carried out in batch reactors, using different reactant molar ratios and the 2nd generation Ru Hoveyda-Grubbs complex as catalyst. Reaction mixtures at the equilibrium were analyzed by gas chromatography. Equilibrium constants were determined by assuming unitary activity coefficients for a cinnamaldehyde/methyl oleate equimolar ratio, and the validity of that approximation was evaluated by calculating the equilibrium conversions for different reactant molar ratios.

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