Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex

The release of uranyl(VI) is a hazardous environmental issue, with limited ways to monitor accumulation in situ. Here, we present a method for the detection of uranyl(VI) ions through the utilization of a unique fluorescence energy transfer process to europium(III). Our system displays the first exa...

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Detalles Bibliográficos
Autores principales: Harvey, Peter, Nonat, Aline, Platas‐Iglesias, Carlos, Natrajan, Louise S., Charbonnière, Loïc J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099227/
https://www.ncbi.nlm.nih.gov/pubmed/29898241
http://dx.doi.org/10.1002/anie.201805316
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author Harvey, Peter
Nonat, Aline
Platas‐Iglesias, Carlos
Natrajan, Louise S.
Charbonnière, Loïc J.
author_facet Harvey, Peter
Nonat, Aline
Platas‐Iglesias, Carlos
Natrajan, Louise S.
Charbonnière, Loïc J.
author_sort Harvey, Peter
collection PubMed
description The release of uranyl(VI) is a hazardous environmental issue, with limited ways to monitor accumulation in situ. Here, we present a method for the detection of uranyl(VI) ions through the utilization of a unique fluorescence energy transfer process to europium(III). Our system displays the first example of a “turn‐on” europium(III) emission process with a small, water‐soluble lanthanide complex triggered by uranyl(VI) ions.
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spelling pubmed-60992272018-08-23 Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex Harvey, Peter Nonat, Aline Platas‐Iglesias, Carlos Natrajan, Louise S. Charbonnière, Loïc J. Angew Chem Int Ed Engl Communications The release of uranyl(VI) is a hazardous environmental issue, with limited ways to monitor accumulation in situ. Here, we present a method for the detection of uranyl(VI) ions through the utilization of a unique fluorescence energy transfer process to europium(III). Our system displays the first example of a “turn‐on” europium(III) emission process with a small, water‐soluble lanthanide complex triggered by uranyl(VI) ions. John Wiley and Sons Inc. 2018-06-29 2018-07-26 /pmc/articles/PMC6099227/ /pubmed/29898241 http://dx.doi.org/10.1002/anie.201805316 Text en © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Harvey, Peter
Nonat, Aline
Platas‐Iglesias, Carlos
Natrajan, Louise S.
Charbonnière, Loïc J.
Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex
title Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex
title_full Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex
title_fullStr Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex
title_full_unstemmed Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex
title_short Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex
title_sort sensing uranyl(vi) ions by coordination and energy transfer to a luminescent europium(iii) complex
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099227/
https://www.ncbi.nlm.nih.gov/pubmed/29898241
http://dx.doi.org/10.1002/anie.201805316
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