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Securing a Supramolecular Architecture by Tying a Stopper Knot
We report on a rotaxane‐like architecture secured by the in situ tying of an overhand knot in the tris(2,6‐pyridyldicarboxamide) region of the axle through complexation with a lanthanide ion (Lu(3+)). The increase in steric bulk caused by the knotting locks a crown ether onto the thread. Removal of...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099318/ https://www.ncbi.nlm.nih.gov/pubmed/29708636 http://dx.doi.org/10.1002/anie.201803871 |