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C−H Borylation/Cross‐Coupling Forms Twisted Donor–Acceptor Compounds Exhibiting Donor‐Dependent Delayed Emission
Benzothiadiazole (BT) directed C−H borylation using BCl(3), followed by B−Cl hydrolysis and Suzuki–Miyaura cross‐coupling enables facile access to twisted donor–acceptor compounds. A subsequent second C−H borylation step provides, on arylation of boron, access to borylated highly twisted D−A compoun...
Autores principales: | Crossley, Daniel L., Kulapichitr, Pakapol, Radcliffe, James E., Dunsford, Jay J., Vitorica‐Yrezabal, Inigo, Kahan, Rachel J., Woodward, Adam W., Turner, Michael L., McDouall, Joseph J. W., Ingleson, Michael J. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099339/ https://www.ncbi.nlm.nih.gov/pubmed/29781115 http://dx.doi.org/10.1002/chem.201801799 |
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