Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis

The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transfo...

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Autores principales: Czaban-Jóźwiak, Justyna, Woźniak, Łukasz, Ulikowski, Artur, Kwiecińska, Katarzyna, Rajkiewicz, Adam A., Grela, Karol
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099925/
https://www.ncbi.nlm.nih.gov/pubmed/30011916
http://dx.doi.org/10.3390/molecules23071722
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author Czaban-Jóźwiak, Justyna
Woźniak, Łukasz
Ulikowski, Artur
Kwiecińska, Katarzyna
Rajkiewicz, Adam A.
Grela, Karol
author_facet Czaban-Jóźwiak, Justyna
Woźniak, Łukasz
Ulikowski, Artur
Kwiecińska, Katarzyna
Rajkiewicz, Adam A.
Grela, Karol
author_sort Czaban-Jóźwiak, Justyna
collection PubMed
description The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds.
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spelling pubmed-60999252018-11-13 Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis Czaban-Jóźwiak, Justyna Woźniak, Łukasz Ulikowski, Artur Kwiecińska, Katarzyna Rajkiewicz, Adam A. Grela, Karol Molecules Article The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds. MDPI 2018-07-14 /pmc/articles/PMC6099925/ /pubmed/30011916 http://dx.doi.org/10.3390/molecules23071722 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Czaban-Jóźwiak, Justyna
Woźniak, Łukasz
Ulikowski, Artur
Kwiecińska, Katarzyna
Rajkiewicz, Adam A.
Grela, Karol
Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title_full Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title_fullStr Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title_full_unstemmed Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title_short Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title_sort modification of polyhedral oligomeric silsesquioxanes (poss) molecules by ruthenium catalyzed cross metathesis
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099925/
https://www.ncbi.nlm.nih.gov/pubmed/30011916
http://dx.doi.org/10.3390/molecules23071722
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