Understanding the Molecule-Electrode Interface for Molecular Spintronic Devices: A Computational and Experimental Study

A triple-decker SYML-Dy2 single-molecule magnet (SMM) was synthetized and grafted onto the surface of iron oxide nanoparticles (IO-NPs) coated by an oleic acid monolayer. The magnetism of the SYML-Dy2 complex, and the hybrid system, NP-Dy2, were studied by a superconducting quantum interference devi...

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Detalles Bibliográficos
Autores principales: Rosado Piquer, Lidia, Sánchez, Raquel Royo, Sañudo, E. Carolina, Echeverría, Jorge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100063/
https://www.ncbi.nlm.nih.gov/pubmed/29899309
http://dx.doi.org/10.3390/molecules23061441
Descripción
Sumario:A triple-decker SYML-Dy2 single-molecule magnet (SMM) was synthetized and grafted onto the surface of iron oxide nanoparticles (IO-NPs) coated by an oleic acid monolayer. The magnetism of the SYML-Dy2 complex, and the hybrid system, NP-Dy2, were studied by a superconducting quantum interference device (SQUID). Density functional theory (DFT) calculations were carried out to study both the energetics of the interaction between SYML-Dy2 complex to the organic capping, and the assembly presented by the oleic acid chains.

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