Understanding the Molecule-Electrode Interface for Molecular Spintronic Devices: A Computational and Experimental Study

A triple-decker SYML-Dy2 single-molecule magnet (SMM) was synthetized and grafted onto the surface of iron oxide nanoparticles (IO-NPs) coated by an oleic acid monolayer. The magnetism of the SYML-Dy2 complex, and the hybrid system, NP-Dy2, were studied by a superconducting quantum interference devi...

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Detalles Bibliográficos
Autores principales: Rosado Piquer, Lidia, Sánchez, Raquel Royo, Sañudo, E. Carolina, Echeverría, Jorge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100063/
https://www.ncbi.nlm.nih.gov/pubmed/29899309
http://dx.doi.org/10.3390/molecules23061441
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author Rosado Piquer, Lidia
Sánchez, Raquel Royo
Sañudo, E. Carolina
Echeverría, Jorge
author_facet Rosado Piquer, Lidia
Sánchez, Raquel Royo
Sañudo, E. Carolina
Echeverría, Jorge
author_sort Rosado Piquer, Lidia
collection PubMed
description A triple-decker SYML-Dy2 single-molecule magnet (SMM) was synthetized and grafted onto the surface of iron oxide nanoparticles (IO-NPs) coated by an oleic acid monolayer. The magnetism of the SYML-Dy2 complex, and the hybrid system, NP-Dy2, were studied by a superconducting quantum interference device (SQUID). Density functional theory (DFT) calculations were carried out to study both the energetics of the interaction between SYML-Dy2 complex to the organic capping, and the assembly presented by the oleic acid chains.
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spelling pubmed-61000632018-11-13 Understanding the Molecule-Electrode Interface for Molecular Spintronic Devices: A Computational and Experimental Study Rosado Piquer, Lidia Sánchez, Raquel Royo Sañudo, E. Carolina Echeverría, Jorge Molecules Article A triple-decker SYML-Dy2 single-molecule magnet (SMM) was synthetized and grafted onto the surface of iron oxide nanoparticles (IO-NPs) coated by an oleic acid monolayer. The magnetism of the SYML-Dy2 complex, and the hybrid system, NP-Dy2, were studied by a superconducting quantum interference device (SQUID). Density functional theory (DFT) calculations were carried out to study both the energetics of the interaction between SYML-Dy2 complex to the organic capping, and the assembly presented by the oleic acid chains. MDPI 2018-06-13 /pmc/articles/PMC6100063/ /pubmed/29899309 http://dx.doi.org/10.3390/molecules23061441 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Rosado Piquer, Lidia
Sánchez, Raquel Royo
Sañudo, E. Carolina
Echeverría, Jorge
Understanding the Molecule-Electrode Interface for Molecular Spintronic Devices: A Computational and Experimental Study
title Understanding the Molecule-Electrode Interface for Molecular Spintronic Devices: A Computational and Experimental Study
title_full Understanding the Molecule-Electrode Interface for Molecular Spintronic Devices: A Computational and Experimental Study
title_fullStr Understanding the Molecule-Electrode Interface for Molecular Spintronic Devices: A Computational and Experimental Study
title_full_unstemmed Understanding the Molecule-Electrode Interface for Molecular Spintronic Devices: A Computational and Experimental Study
title_short Understanding the Molecule-Electrode Interface for Molecular Spintronic Devices: A Computational and Experimental Study
title_sort understanding the molecule-electrode interface for molecular spintronic devices: a computational and experimental study
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100063/
https://www.ncbi.nlm.nih.gov/pubmed/29899309
http://dx.doi.org/10.3390/molecules23061441
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