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One-Dimensional (13)C NMR Is a Simple and Highly Quantitative Method for Enantiodiscrimination

The discrimination of enantiomers of mandelonitrile by means of 1D (13)C NMR and with the aid of the chiral solvating agent (S)-(+)-1-(9-anthryl)-2,2,2-trifluoroethanol (TFAE) is presented. (1)H NMR fails for this specific compound because proton signals either overlap with the signals of the chiral...

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Detalles Bibliográficos
Autores principales:	Lankhorst, Peter P., van Rijn, Jozef H. J., Duchateau, Alexander L. L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2018
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100457/ https://www.ncbi.nlm.nih.gov/pubmed/30036942 http://dx.doi.org/10.3390/molecules23071785

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