Cargando…
Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions
Novel complexes of 1,2-P,N-bidentate ferrocenyl ligands with AgOAc or with [RuCl(2)(PPh(3))(3)] as catalysts have been studied in asymmetric synthesis. The catalytic activity of these systems have been studied in [3+2]-cycloaddition of azomethine ylides with olefins and the asymmetric transfer hydro...
Autores principales: | , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100496/ https://www.ncbi.nlm.nih.gov/pubmed/29848984 http://dx.doi.org/10.3390/molecules23061311 |
_version_ | 1783348887950458880 |
---|---|
author | Utepova, Irina A. Serebrennikova, Polina O. Streltsova, Marina S. Musikhina, Alexandra A. Fedorchenko, Tatiana G. Chupakhin, Oleg N. Antonchick, Andrey P. |
author_facet | Utepova, Irina A. Serebrennikova, Polina O. Streltsova, Marina S. Musikhina, Alexandra A. Fedorchenko, Tatiana G. Chupakhin, Oleg N. Antonchick, Andrey P. |
author_sort | Utepova, Irina A. |
collection | PubMed |
description | Novel complexes of 1,2-P,N-bidentate ferrocenyl ligands with AgOAc or with [RuCl(2)(PPh(3))(3)] as catalysts have been studied in asymmetric synthesis. The catalytic activity of these systems have been studied in [3+2]-cycloaddition of azomethine ylides with olefins and the asymmetric transfer hydrogenation of ketones. |
format | Online Article Text |
id | pubmed-6100496 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-61004962018-11-13 Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions Utepova, Irina A. Serebrennikova, Polina O. Streltsova, Marina S. Musikhina, Alexandra A. Fedorchenko, Tatiana G. Chupakhin, Oleg N. Antonchick, Andrey P. Molecules Article Novel complexes of 1,2-P,N-bidentate ferrocenyl ligands with AgOAc or with [RuCl(2)(PPh(3))(3)] as catalysts have been studied in asymmetric synthesis. The catalytic activity of these systems have been studied in [3+2]-cycloaddition of azomethine ylides with olefins and the asymmetric transfer hydrogenation of ketones. MDPI 2018-05-30 /pmc/articles/PMC6100496/ /pubmed/29848984 http://dx.doi.org/10.3390/molecules23061311 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Utepova, Irina A. Serebrennikova, Polina O. Streltsova, Marina S. Musikhina, Alexandra A. Fedorchenko, Tatiana G. Chupakhin, Oleg N. Antonchick, Andrey P. Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions |
title | Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions |
title_full | Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions |
title_fullStr | Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions |
title_full_unstemmed | Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions |
title_short | Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions |
title_sort | enantiomerically enriched 1,2-p,n-bidentate ferrocenyl ligands for 1,3-dipolar cycloaddition and transfer hydrogenation reactions |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100496/ https://www.ncbi.nlm.nih.gov/pubmed/29848984 http://dx.doi.org/10.3390/molecules23061311 |
work_keys_str_mv | AT utepovairinaa enantiomericallyenriched12pnbidentateferrocenylligandsfor13dipolarcycloadditionandtransferhydrogenationreactions AT serebrennikovapolinao enantiomericallyenriched12pnbidentateferrocenylligandsfor13dipolarcycloadditionandtransferhydrogenationreactions AT streltsovamarinas enantiomericallyenriched12pnbidentateferrocenylligandsfor13dipolarcycloadditionandtransferhydrogenationreactions AT musikhinaalexandraa enantiomericallyenriched12pnbidentateferrocenylligandsfor13dipolarcycloadditionandtransferhydrogenationreactions AT fedorchenkotatianag enantiomericallyenriched12pnbidentateferrocenylligandsfor13dipolarcycloadditionandtransferhydrogenationreactions AT chupakhinolegn enantiomericallyenriched12pnbidentateferrocenylligandsfor13dipolarcycloadditionandtransferhydrogenationreactions AT antonchickandreyp enantiomericallyenriched12pnbidentateferrocenylligandsfor13dipolarcycloadditionandtransferhydrogenationreactions |