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Hydride oxidation from a titanium–aluminum bimetallic complex: insertion, thermal and electrochemical reactivity
We report the synthesis and reactivity of paramagnetic heterometallic complexes containing a Ti(iii)-μ-H-Al(iii) moiety. Combining different stoichiometries amounts of Cp(2)TiCl and KH(3)AlC(TMS)(3) (Cp = cyclopentadienyl, TMS = trimethylsilyl) resulted in the formation of either bimetallic Cp(2)Ti(...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6102661/ https://www.ncbi.nlm.nih.gov/pubmed/30155225 http://dx.doi.org/10.1039/c7sc01835e |