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Hydride oxidation from a titanium–aluminum bimetallic complex: insertion, thermal and electrochemical reactivity

We report the synthesis and reactivity of paramagnetic heterometallic complexes containing a Ti(iii)-μ-H-Al(iii) moiety. Combining different stoichiometries amounts of Cp(2)TiCl and KH(3)AlC(TMS)(3) (Cp = cyclopentadienyl, TMS = trimethylsilyl) resulted in the formation of either bimetallic Cp(2)Ti(...

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Detalles Bibliográficos
Autores principales: Brown, Alexandra C., Altman, Alison B., Lohrey, Trevor D., Hohloch, Stephan, Arnold, John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6102661/
https://www.ncbi.nlm.nih.gov/pubmed/30155225
http://dx.doi.org/10.1039/c7sc01835e

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