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Reactivity of Two-Electron-Reduced Boron Formazanate Compounds with Electrophiles: Facile N–H/N–C Bond Homolysis Due to the Formation of Stable Ligand Radicals
[Image: see text] The reactivity of a boron complex with a redox-active formazanate ligand, LBPh(2) [L = PhNNC(p-tol)NNPh], was studied. Two-electron reduction of this main-group complex generates the stable, nucleophilic dianion [LBPh(2)](2–), which reacts with the electrophiles BnBr and H(2)O to f...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6106049/ https://www.ncbi.nlm.nih.gov/pubmed/29446931 http://dx.doi.org/10.1021/acs.inorgchem.8b00079 |