Porphyrinic Ionic Liquid Dyes: Synthesis and Characterization

Four porphyrinic ionic liquids and four higher melting salts (>100 °C) were synthesized as potential photosensitizers from highly symmetric porphyrins by introducing alkyl chains and exchanging anions to tune their solubility and singlet oxygen generation capability. Among the synthesized compoun...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Kai, Titi, Hatem M., Berton, Paula, Rogers, Robin D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6110049/
https://www.ncbi.nlm.nih.gov/pubmed/30155400
http://dx.doi.org/10.1002/open.201800166
_version_ 1783350412843155456
author Li, Kai
Titi, Hatem M.
Berton, Paula
Rogers, Robin D.
author_facet Li, Kai
Titi, Hatem M.
Berton, Paula
Rogers, Robin D.
author_sort Li, Kai
collection PubMed
description Four porphyrinic ionic liquids and four higher melting salts (>100 °C) were synthesized as potential photosensitizers from highly symmetric porphyrins by introducing alkyl chains and exchanging anions to tune their solubility and singlet oxygen generation capability. Among the synthesized compounds was 5,10,15,20‐tetra(4‐dodecylpyridinum)porphyrin tetrakis‐bis(trifluoromethylsulfonyl)‐amide, a room‐temperature ionic liquid that could be crystallized as a solvate with nitrobenzene.
format Online
Article
Text
id pubmed-6110049
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-61100492018-08-28 Porphyrinic Ionic Liquid Dyes: Synthesis and Characterization Li, Kai Titi, Hatem M. Berton, Paula Rogers, Robin D. ChemistryOpen Communications Four porphyrinic ionic liquids and four higher melting salts (>100 °C) were synthesized as potential photosensitizers from highly symmetric porphyrins by introducing alkyl chains and exchanging anions to tune their solubility and singlet oxygen generation capability. Among the synthesized compounds was 5,10,15,20‐tetra(4‐dodecylpyridinum)porphyrin tetrakis‐bis(trifluoromethylsulfonyl)‐amide, a room‐temperature ionic liquid that could be crystallized as a solvate with nitrobenzene. John Wiley and Sons Inc. 2018-08-27 /pmc/articles/PMC6110049/ /pubmed/30155400 http://dx.doi.org/10.1002/open.201800166 Text en © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Li, Kai
Titi, Hatem M.
Berton, Paula
Rogers, Robin D.
Porphyrinic Ionic Liquid Dyes: Synthesis and Characterization
title Porphyrinic Ionic Liquid Dyes: Synthesis and Characterization
title_full Porphyrinic Ionic Liquid Dyes: Synthesis and Characterization
title_fullStr Porphyrinic Ionic Liquid Dyes: Synthesis and Characterization
title_full_unstemmed Porphyrinic Ionic Liquid Dyes: Synthesis and Characterization
title_short Porphyrinic Ionic Liquid Dyes: Synthesis and Characterization
title_sort porphyrinic ionic liquid dyes: synthesis and characterization
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6110049/
https://www.ncbi.nlm.nih.gov/pubmed/30155400
http://dx.doi.org/10.1002/open.201800166
work_keys_str_mv AT likai porphyrinicionicliquiddyessynthesisandcharacterization
AT titihatemm porphyrinicionicliquiddyessynthesisandcharacterization
AT bertonpaula porphyrinicionicliquiddyessynthesisandcharacterization
AT rogersrobind porphyrinicionicliquiddyessynthesisandcharacterization

Ejemplares similares