Thermally-Induced Spin Crossover and LIESST Effect in the Neutral [Fe(II)((Me)bik)(2)(NCX)(2)] Complexes: Variable-Temperature Structural, Magnetic, and Optical Studies (X = S, Se; (Me)bik = bis(1-methylimidazol-2-yl)ketone)

Two new iron(II) neutral complexes of bis(1-methylimidazol-2-yl)ketone ((Me)bik) with molecular formula [Fe(II)((Me)bik)(2)(NCS)(2)] (1) and [Fe(II)((Me)bik)(2)(NCSe)(2)] (2) have been synthesized and characterized by magnetic measurements, single-crystal X-ray diffraction, and solid state UV-vis sp...

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Detalles Bibliográficos
Autores principales: De, Siddhartha, Chamoreau, Lise-Marie, El Said, Hasnaa, Li, Yanling, Flambard, Alexandrine, Boillot, Marie-Laure, Tewary, Subrata, Rajaraman, Gopalan, Lescouëzec, Rodrigue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6111792/
https://www.ncbi.nlm.nih.gov/pubmed/30186827
http://dx.doi.org/10.3389/fchem.2018.00326

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