Bench-Stable Nickel Precatalysts with Heck-type Activation

[Image: see text] Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl–ene coupling reaction.

Detalles Bibliográficos
Autores principales: Weber, Jessica M., Longstreet, Ashley R., Jamison, Timothy F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6113681/
https://www.ncbi.nlm.nih.gov/pubmed/30174368
http://dx.doi.org/10.1021/acs.organomet.8b00351
Descripción
Sumario:[Image: see text] Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl–ene coupling reaction.

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