Cargando…
Bench-Stable Nickel Precatalysts with Heck-type Activation
[Image: see text] Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl–ene coupling reaction.
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2018
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6113681/ https://www.ncbi.nlm.nih.gov/pubmed/30174368 http://dx.doi.org/10.1021/acs.organomet.8b00351 |
| _version_ | 1783351052989366272 |
|---|---|
| author | Weber, Jessica M. Longstreet, Ashley R. Jamison, Timothy F. |
| author_facet | Weber, Jessica M. Longstreet, Ashley R. Jamison, Timothy F. |
| author_sort | Weber, Jessica M. |
| collection | PubMed |
| description | [Image: see text] Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl–ene coupling reaction. |
| format | Online Article Text |
| id | pubmed-6113681 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2018 |
| publisher | American
Chemical Society |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-61136812018-08-30 Bench-Stable Nickel Precatalysts with Heck-type Activation Weber, Jessica M. Longstreet, Ashley R. Jamison, Timothy F. Organometallics [Image: see text] Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl–ene coupling reaction. American Chemical Society 2018-08-09 2018-08-27 /pmc/articles/PMC6113681/ /pubmed/30174368 http://dx.doi.org/10.1021/acs.organomet.8b00351 Text en Copyright © 2018 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited. |
| spellingShingle | Weber, Jessica M. Longstreet, Ashley R. Jamison, Timothy F. Bench-Stable Nickel Precatalysts with Heck-type Activation |
| title | Bench-Stable Nickel Precatalysts with Heck-type Activation |
| title_full | Bench-Stable Nickel Precatalysts with Heck-type Activation |
| title_fullStr | Bench-Stable Nickel Precatalysts with Heck-type Activation |
| title_full_unstemmed | Bench-Stable Nickel Precatalysts with Heck-type Activation |
| title_short | Bench-Stable Nickel Precatalysts with Heck-type Activation |
| title_sort | bench-stable nickel precatalysts with heck-type activation |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6113681/ https://www.ncbi.nlm.nih.gov/pubmed/30174368 http://dx.doi.org/10.1021/acs.organomet.8b00351 |
| work_keys_str_mv | AT weberjessicam benchstablenickelprecatalystswithhecktypeactivation AT longstreetashleyr benchstablenickelprecatalystswithhecktypeactivation AT jamisontimothyf benchstablenickelprecatalystswithhecktypeactivation |