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Bench-Stable Nickel Precatalysts with Heck-type Activation
[Image: see text] Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl–ene coupling reaction.
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6113681/ https://www.ncbi.nlm.nih.gov/pubmed/30174368 http://dx.doi.org/10.1021/acs.organomet.8b00351 |