Probing the oxidation state of transition metal complexes: a case study on how charge and spin densities determine Mn L-edge X-ray absorption energies

Transition metals in inorganic systems and metalloproteins can occur in different oxidation states, which makes them ideal redox-active catalysts. To gain a mechanistic understanding of the catalytic reactions, knowledge of the oxidation state of the active metals, ideally in operando, is therefore...

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Detalles Bibliográficos
Autores principales: Kubin, Markus, Guo, Meiyuan, Kroll, Thomas, Löchel, Heike, Källman, Erik, Baker, Michael L., Mitzner, Rolf, Gul, Sheraz, Kern, Jan, Föhlisch, Alexander, Erko, Alexei, Bergmann, Uwe, Yachandra, Vittal, Yano, Junko, Lundberg, Marcus, Wernet, Philippe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115617/
https://www.ncbi.nlm.nih.gov/pubmed/30310614
http://dx.doi.org/10.1039/c8sc00550h

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