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Synthesis and structural characterization of inverse-coordination clusters from a two-electron superatomic copper nanocluster
We have synthesized and structurally characterized a series of centred cuboctahedral copper clusters, namely [Cu(13){S(2)CNR(2)}(6){C[triple bond, length as m-dash]CR′}(4)](PF(6)), 1a–d (where a: R = (n)Bu, R′ = CO(2)Me; b: R = (n)Bu, R′ = CO(2)Et; c: R = (i)Pr, R′ = CO(2)Et; d: R = (n)Pr, R′ = 3,5-...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115619/ https://www.ncbi.nlm.nih.gov/pubmed/30310611 http://dx.doi.org/10.1039/c8sc01508b |