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Slow magnetic relaxation in octahedral low-spin Ni(iii) complexes

Herein we report the first examples of single-molecule magnet (SMM) behaviour in S = 1/2 Ni(iii) complexes. We find that low-spin 3d(7)trans-[Ni(III)(cyclam)(X)(2)]Y complexes (cyclam = 1,4,8,11-tetraazacyclotetradecane; X and Y are singly charged anions) exhibit field-induced slow relaxation of mag...

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Detalles Bibliográficos
Autores principales:	Bhowmick, Indrani, Roehl, Andrew J., Neilson, James R., Rappé, Anthony K., Shores, Matthew P.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115677/ https://www.ncbi.nlm.nih.gov/pubmed/30310588 http://dx.doi.org/10.1039/c7sc04482h

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