Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N(2)O reduction

The thiohyponitrite ([SNNO](2–)) complex, [K(18-crown-6)][L(tBu)Ni(II)(κ(2)-SNNO)] (L(tBu) = {(2,6-(i)Pr(2)C(6)H(3))NC((t)Bu)}(2)CH), extrudes N(2) under mild heating to yield [K(18-crown-6)][L(tBu)Ni(II)(η(2)-SO)] (1), along with minor products [K(18-crown-6)][L(tBu)Ni(II)(η(2)-OSSO)] (2) and [K(18...

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Detalles Bibliográficos
Autores principales: Hartmann, Nathaniel J., Wu, Guang, Hayton, Trevor W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115681/
https://www.ncbi.nlm.nih.gov/pubmed/30310590
http://dx.doi.org/10.1039/c8sc02536c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115681/
https://www.ncbi.nlm.nih.gov/pubmed/30310590
http://dx.doi.org/10.1039/c8sc02536c

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