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Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N(2)O reduction
The thiohyponitrite ([SNNO](2–)) complex, [K(18-crown-6)][L(tBu)Ni(II)(κ(2)-SNNO)] (L(tBu) = {(2,6-(i)Pr(2)C(6)H(3))NC((t)Bu)}(2)CH), extrudes N(2) under mild heating to yield [K(18-crown-6)][L(tBu)Ni(II)(η(2)-SO)] (1), along with minor products [K(18-crown-6)][L(tBu)Ni(II)(η(2)-OSSO)] (2) and [K(18...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115681/ https://www.ncbi.nlm.nih.gov/pubmed/30310590 http://dx.doi.org/10.1039/c8sc02536c |