How can infra-red excitation both accelerate and slow charge transfer in the same molecule?

A UV-IR-Vis 3-pulse study of infra-red induced changes to electron transfer (ET) rates in a donor–bridge–acceptor species finds that charge-separation rates are slowed, while charge-recombination rates are accelerated as a result of IR excitation during the reaction. We explore the underpinning mech...

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Detalles Bibliográficos
Autores principales: Ma, Zheng, Lin, Zhiwei, Lawrence, Candace M., Rubtsov, Igor V., Antoniou, Panayiotis, Skourtis, Spiros S., Zhang, Peng, Beratan, David N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115705/
https://www.ncbi.nlm.nih.gov/pubmed/30310568
http://dx.doi.org/10.1039/c8sc00092a

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