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Micro/Mesoporous Fe(3)O(4)/Fe-Phthalocyanine Microspheres and Effects of Their Surface Morphology on the Crystallization and Properties of Poly(Arylene Ether Nitrile) Composites
The surface morphology of nanoparticles significantly affects the final properties and interfacial characteristics of their composites. Thus, investigations on the surface morphology of the nanoparticles is essential to fabricate improved nanoparticle-reinforced composites. Fe(3)O(4)/Fe-phthalocyani...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6119999/ https://www.ncbi.nlm.nih.gov/pubmed/30081589 http://dx.doi.org/10.3390/ma11081356 |
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author | Li, Kui Ren, Dengxun Tang, Xianzhong Xu, Mingzhen Liu, Xiaobo |
author_facet | Li, Kui Ren, Dengxun Tang, Xianzhong Xu, Mingzhen Liu, Xiaobo |
author_sort | Li, Kui |
collection | PubMed |
description | The surface morphology of nanoparticles significantly affects the final properties and interfacial characteristics of their composites. Thus, investigations on the surface morphology of the nanoparticles is essential to fabricate improved nanoparticle-reinforced composites. Fe(3)O(4)/Fe-phthalocyanine (FePc) hybrid microspheres with micro/mesoporous structures were prepared via a solvothermal process and solvent etching method. The surface morphology and compositional distribution were respectively investigated using a scanning electron microscope (SEM) and a transmission electron microscope (TEM) to rule out that FePc monomers have been blended with Fe(3)O(4) to form Fe(3)O(4)/FePc hybrid microspheres without serious agglomeration. The surface roughness of Fe(3)O(4)/FePc microspheres was investigated by the scanning probe microscope (SPM), and confirmed by the adsorption and desorption isotherms of N(2). The effects of the various surface morphologies on the crystallization behavior of crystallizable poly(arylene ether nitrile) (c-PEN) were first employed to confirm the surface characteristics of the resulted microspheres. Results indicated that the etched Fe(3)O(4)/FePc microspheres would improve the crystallization degree of c-PEN, due to their much more micro/mesoporous structures than that of original Fe(3)O(4)/FePc. Then, Fe(3)O(4)/FePc hybrid microspheres reinforced PEN composite films were prepared and their interfacial compatibility was monitored using an SEM. Excellent thermal stability and improved mechanical properties were obtained by combining the etched Fe(3)O(4)/FePc and PEN matrix. The excellent surface properties and micro/mesoporous structures make the novel Fe(3)O(4)/FePc an excellent candidate of organic/inorganic hybrid fillers and micro/mesoporous materials. |
format | Online Article Text |
id | pubmed-6119999 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-61199992018-09-05 Micro/Mesoporous Fe(3)O(4)/Fe-Phthalocyanine Microspheres and Effects of Their Surface Morphology on the Crystallization and Properties of Poly(Arylene Ether Nitrile) Composites Li, Kui Ren, Dengxun Tang, Xianzhong Xu, Mingzhen Liu, Xiaobo Materials (Basel) Article The surface morphology of nanoparticles significantly affects the final properties and interfacial characteristics of their composites. Thus, investigations on the surface morphology of the nanoparticles is essential to fabricate improved nanoparticle-reinforced composites. Fe(3)O(4)/Fe-phthalocyanine (FePc) hybrid microspheres with micro/mesoporous structures were prepared via a solvothermal process and solvent etching method. The surface morphology and compositional distribution were respectively investigated using a scanning electron microscope (SEM) and a transmission electron microscope (TEM) to rule out that FePc monomers have been blended with Fe(3)O(4) to form Fe(3)O(4)/FePc hybrid microspheres without serious agglomeration. The surface roughness of Fe(3)O(4)/FePc microspheres was investigated by the scanning probe microscope (SPM), and confirmed by the adsorption and desorption isotherms of N(2). The effects of the various surface morphologies on the crystallization behavior of crystallizable poly(arylene ether nitrile) (c-PEN) were first employed to confirm the surface characteristics of the resulted microspheres. Results indicated that the etched Fe(3)O(4)/FePc microspheres would improve the crystallization degree of c-PEN, due to their much more micro/mesoporous structures than that of original Fe(3)O(4)/FePc. Then, Fe(3)O(4)/FePc hybrid microspheres reinforced PEN composite films were prepared and their interfacial compatibility was monitored using an SEM. Excellent thermal stability and improved mechanical properties were obtained by combining the etched Fe(3)O(4)/FePc and PEN matrix. The excellent surface properties and micro/mesoporous structures make the novel Fe(3)O(4)/FePc an excellent candidate of organic/inorganic hybrid fillers and micro/mesoporous materials. MDPI 2018-08-05 /pmc/articles/PMC6119999/ /pubmed/30081589 http://dx.doi.org/10.3390/ma11081356 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Li, Kui Ren, Dengxun Tang, Xianzhong Xu, Mingzhen Liu, Xiaobo Micro/Mesoporous Fe(3)O(4)/Fe-Phthalocyanine Microspheres and Effects of Their Surface Morphology on the Crystallization and Properties of Poly(Arylene Ether Nitrile) Composites |
title | Micro/Mesoporous Fe(3)O(4)/Fe-Phthalocyanine Microspheres and Effects of Their Surface Morphology on the Crystallization and Properties of Poly(Arylene Ether Nitrile) Composites |
title_full | Micro/Mesoporous Fe(3)O(4)/Fe-Phthalocyanine Microspheres and Effects of Their Surface Morphology on the Crystallization and Properties of Poly(Arylene Ether Nitrile) Composites |
title_fullStr | Micro/Mesoporous Fe(3)O(4)/Fe-Phthalocyanine Microspheres and Effects of Their Surface Morphology on the Crystallization and Properties of Poly(Arylene Ether Nitrile) Composites |
title_full_unstemmed | Micro/Mesoporous Fe(3)O(4)/Fe-Phthalocyanine Microspheres and Effects of Their Surface Morphology on the Crystallization and Properties of Poly(Arylene Ether Nitrile) Composites |
title_short | Micro/Mesoporous Fe(3)O(4)/Fe-Phthalocyanine Microspheres and Effects of Their Surface Morphology on the Crystallization and Properties of Poly(Arylene Ether Nitrile) Composites |
title_sort | micro/mesoporous fe(3)o(4)/fe-phthalocyanine microspheres and effects of their surface morphology on the crystallization and properties of poly(arylene ether nitrile) composites |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6119999/ https://www.ncbi.nlm.nih.gov/pubmed/30081589 http://dx.doi.org/10.3390/ma11081356 |
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