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The Chirality Chain in Valine: How the Configuration at the C(α) Position through the O(cis)C′C(α)N Torsional System Leads to Distortion of the Planar Group C(α)C′(O(cis))O(trans) to a Flat Tetrahedron
Solid‐state structures, based on a Cambridge Structural Database (CSD) search, show that there is a C(α)N/C′O(cis) attraction in the torsional system O(cis)C′C(α)N of valine, causing a chirality chain. The C(α) configuration controls the chirality of the rotation around the C′−C(α) bond, which in tu...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6120350/ https://www.ncbi.nlm.nih.gov/pubmed/30186736 http://dx.doi.org/10.1002/open.201800137 |