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Dimethylcethrene: A Chiroptical Diradicaloid Photoswitch
[Image: see text] We describe the synthesis and properties of 13,14-dimethylcethrene, a prototype of a chiral diradicaloid photochemical switch that can be transformed reversibly via conrotatory electrocyclization to its more stable closed form by light (630 nm) or heat and back to its open form by...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6120736/ https://www.ncbi.nlm.nih.gov/pubmed/30067898 http://dx.doi.org/10.1021/jacs.8b05465 |