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D-Fructose-based spiro-fused PHOX ligands: synthesis and application in enantioselective allylic alkylation
Phosphinooxazoline (PHOX) ligands are an important class of ligands in asymmetric catalysis. We synthesized ten novel D-fructose-derived spiro-fused PHOX ligands with different steric and electronic demand. The application of two of them was tested in asymmetric allylic alkylation. The ligands are p...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122323/ https://www.ncbi.nlm.nih.gov/pubmed/30202461 http://dx.doi.org/10.3762/bjoc.14.182 |